1.2.5

Trends in the Periodic Table

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Atomic Radius

There are key trends in atomic radius as we go across periods and when we go down groups.

Periodic trend

Periodic trend

Atomic radius decreases along a period.
- This is because the number of protons in the nucleus increases across the period.
- As you add protons, you also add electrons. But these are all being added to the same shell, so this does not affect the radius.
So each electron feels a stronger attraction to the nucleus and is held closer.

Periodic example

Periodic example

In Period 3, sulfur has a smaller atomic radius than phosphorus.
Sulfur has one more electron but still only fills up the same shell (3p) as phosphorus, so the radius is not affected.
But sulfur has one more proton than phosphorus - this does affect the radius.
- Sulfur has a greater nuclear charge because of having more protons.
- This pulls the electrons closer.
- This means the atomic radius is smaller.

Group trend

Group trend

Atomic radius increases down a group.
- This is because the number of electron shells increases down a group.
- Each subsequent electron shell is further from the nucleus.
  - This effect outweighs the increase in proton number down the group.

Group example

Group example

In Group 2, magnesium has a larger radius than beryllium.
- Magnesium has more electrons than beryllium and they occupy an additional electron shell.
- The extra electron shell is further from the nucleus.
  - So the atomic radius is larger.

Ionisation Energy

We see trends in ionisation energy across the periods and down the groups of the periodic table.

Periodic trend

Periodic trend

Ionisation energy increases along a period.
- This is because the electrostatic attraction of each electron to the nucleus increases.
- The attraction increases because the proton number increases.

Periodic example

Periodic example

In Period 3, chlorine has a greater nuclear charge than sulfur because it has a greater proton number.
So the electrostatic charge between electrons and the nucleus in chlorine will be greater.
- So the ionisation energy is greater.

Group trend

Group trend

Ionisation energy decreases down a group.
- This is because the outer electron is further from the nucleus down the group.
- The electrostatic attraction of the outer electron to the nucleus decreases down the group.

Group example

Group example

In Group 2, magnesium is below beryllium.
- Magnesium fills up an extra electron shell than beryllium.
- This means an electron is further from the nucleus in magnesium and so the electrostatic attraction is less.
  - So the ionisation energy of magnesium is lower than beryllium.

Melting Points

There are clear trends in the melting points across periods and down groups in the periodic table. We look at Period 3 to see this trend.

Structure on melting point

Structure on melting point

For metals:
- The greater the number of valence electrons, the greater the melting point.
For covalent compounds:
- Molecular solids have low melting points.
- Giant covalent structures have relatively high melting points.

Period trend

Period trend

As you move along a period, you go from metals to giant covalent structures, to molecular solids.
Using our knowledge of melting points of different structures from the previous slide:
- The melting points increase, peak sharply, and then decrease.
We will look at Period 3 to showcase this trend.

Na, Mg, Al

Na, Mg, Al

These all have metallic structures.
Melting point and boiling point increase from Na to Al.
- This is because each element donates one more electron to the sea of free electrons.
- The electrostatic attractions are greater, so the melting point rises.

Si

Silicon has the highest melting point.
- This is because it has a giant covalent structure.
- To melt silicon, you must break strong covalent bonds, which requires a lot of energy.

P, S, Cl, Ar

P, S, Cl, Ar

These elements are simple molecules.
They are held together by Van der Waals forces.
- Sulfur has the highest melting point of the four because it exists as molecules of S₈.
- This means it has a lot of electrons per molecule, so has stronger Van der Waals attractions.
- By contrast, P exists as P₄ and Cl exists as Cl₂.

1

Principles of Science I

1.1

Structure & Bonding

1.1.1Atomic Model 1.1.2Electron Shells, Sub-Shells & Orbitals 1.1.3Ionic Bonding 1.1.4Representing Ionic Bonds 1.1.5Covalent Bonding 1.1.6Representing Covalent Bonds 1.1.7Metallic Bonding 1.1.8Intermolecular Forces 1.1.9Intermolecular Forces 2 1.1.10End of Topic Test - Bonding 1.1.11Relative Masses 1.1.12The Mole 1.1.13Molar Calculations 1.1.14Molar Calculations 2 1.1.15Empirical & Molecular Formulae 1.1.16Balanced Equations 1.1.17Percentage Yield 1.1.18End of Topic Test - Amount of Substance

1.2

Properties of Substances

1.2.1The Periodic Table 1.2.2Ionisation Energy 1.2.3Factors Affecting Ionisation Energies 1.2.4Trends of Ionisation 1.2.5Trends in the Periodic Table 1.2.6Polarity 1.2.7Metals & Non-Metals 1.2.8Alkali Metals 1.2.9Alkaline Earth Metals 1.2.10Reactivity of Alkaline Earth Metals 1.2.11Redox 1.2.12Transition Metals 1.2.13Redox Reactions of Transition Metals

1.3

Cell Structure & Function

1.3.1Introduction to Cells 1.3.2Prokaryotes 1.3.3Organelles of Eukaryotic Cells 1.3.4Organelles of Eukaryotic Cells 2 1.3.5Organelles in Plant Cells 1.3.6Microscopy 1.3.7End of Topic Test - Cell Structure

1.4

Cell Specialisation

1.4.1Cell Specialisation 1.4.2Blood Cells 1.4.3Plant Cells 1.4.4Gametes

1.5

Tissue Structure & Function

1.5.1Human Gas Exchange 1.5.2Blood Vessels 1.5.3Atherosclerosis 1.5.4Skeletal Muscle 1.5.5Slow & Fast Twitch Fibres 1.5.6Neurones 1.5.7Speed of Transmission 1.5.8Action Potentials 1.5.9End of Topic Test - Neurones & Action Potentials 1.5.10Synapses 1.5.11Types of Synapse 1.5.12Medical Application 1.5.13End of Topic Test - Synapses 1.5.14Chemical Brain Imbalances 1.5.15Effect of Drugs on the Brain

1.6

Working with Waves

1.6.1Progressive Waves 1.6.2Wave Speed & Phase Difference 1.6.3Longitudinal & Transverse Waves 1.6.4Stationary Waves 1.6.5Stationary Waves 2 1.6.6Applications of Stationary Waves 1.6.7Interference 1.6.8Diffraction 1.6.9Diffraction Gratings 1.6.10Application of Diffraction Gratings

1.7

Waves in Communication

1.7.1Refraction at a Plane Surface 1.7.2Internal Reflection & Fibre Optics 1.7.3Applications of Total Internal Reflection 1.7.4Properties 1.7.5Gamma, X-Ray & UV Light 1.7.6Visible Light 1.7.7Infrared, Microwave & Radio Waves 1.7.8Intensity 1.7.9Digital & Analogue Signals 1.7.10Communication Channels

2

Practical Scientific Procedures and Techniques

2.1

Titration

2.1.1pH Curves & Titrations 2.1.2pH Curves & Titrations 2 2.1.3Buffer Solutions

2.2

Colorimetry

2.2.1Measuring Rates 2.2.2Beer-Lambert Law

2.3

Chromatography

2.3.1Overview of Chromatography 2.3.2Thin-Layer Chromatography 2.3.3Column Chromatography 2.3.4Gas Chromatography

3

Science Investigation Skills

3.1

Scientific Processes

3.1.1Aims, Hypotheses & Sampling 3.1.2Pilot Studies & Design 3.1.3Ethics 3.1.4Variables & Control 3.1.5Demand Characteristics & Investigator Effects 3.1.6Features of Science 3.1.7Scientific Report 3.1.8Scientific Report 2

3.2

Data Handling & Analysis

3.2.1Types of Data 3.2.2Descriptive Statistics 3.2.3Presentation & Display of Data

3.3

Enzymes in Action

3.3.1Overview of Protein Structure 3.3.2Enzymes 3.3.3Factors Affecting Enzyme Activity 3.3.4Enzyme-Controlled Reactions

3.4

Diffusion

3.5

Plants & Their Environment

3.5.1Factors Affecting Plant Growth 3.5.2Measuring Number & Distribution of Species

3.6

Energy Content in Fuels

3.6.1Fractions 3.6.2Burning Hydrocarbons 3.6.3Combustion 3.6.4Energy 3.6.5Energy at Home 3.6.6Calorimetry

3.7

Electrical Circuits

3.7.1Circuit Diagrams & Components 3.7.2Diodes, LDRs & Thermistors 3.7.3Resistance 3.7.4Electrical Work 3.7.5Ohm's Law 3.7.6Domestic Uses of Electricity 3.7.7Fuses

4

Principles of Science II

4.1

Extracting Elements

4.1.1Atom Economy

4.2

Relating Properties to use of Substances

4.2.1Group 2 Chemistry 4.2.2End of Topic Test - Group 2 4.2.3Electrolysis 4.2.4Electrolysis Examples 4.2.5Extracting Metals 4.2.6Transition Metals 4.2.7Variable Oxidation States 4.2.8Heterogeneous Catalysts 4.2.9Homogeneous Catalysts

4.3

Organic Chemistry

4.3.1Naming Compounds 4.3.2Functional Groups 4.3.3Isomerism 4.3.4Hydrocarbons 4.3.5Structure of Alkanes 4.3.6Boiling Points of Alkanes 4.3.7Alkenes 4.3.8Curly Arrows & Mechanisms 4.3.9Cracking 4.3.10Combustion 4.3.11Free Radical Substitution of Alkanes 4.3.12Electrophilic Addition of Alkenes

4.4

Energy Changes in Industry

4.4.1The Kelvin Scale 4.4.2Enthalpy Changes 4.4.3Calorimetry 4.4.4Bond Enthalpies 4.4.5Hess' Law

4.5

The Circulatory System

4.5.1The Circulatory System 4.5.2Blood Vessels 4.5.3Blood Transfusion & the ABO Rhesus System 4.5.4The Heart 4.5.5The Cardiac Cycle 4.5.6Cardiac Output 4.5.7Coordination of Heart Action 4.5.8Heart Dissection 4.5.9Controlling Heart Rate 4.5.10Electrocardiograms 4.5.11Cardiovascular Disease 4.5.12Investigating Heart Rates

4.6

Ventilation & Gas Exchange

4.6.1Human Gas Exchange 4.6.2Ventilation 4.6.3Measuring Gas Exchange 4.6.4Controlling Ventilation Rate 4.6.5Lung Disease 4.6.6Lung Disease Data

4.7

Urinary System

4.7.1Kidneys & Control of Water Balance 4.7.2Kidneys & Osmoregulation 4.7.3Kidneys & Blood Pressure 4.7.4Urine 4.7.5Kidney Failure & Urinalysis 4.7.6Dialysis 4.7.7Transplants

4.8

Cell Transport

4.8.1Cell Membrane Structure 4.8.2Diffusion 4.8.3Osmosis 4.8.4Active Transport

4.9

Thermal Physics

4.9.1Power & Efficiency 4.9.2Work & Energy 4.9.3Conservation of Energy 4.9.4Pressure 4.9.5First Law of Thermodynamics 4.9.6Second Law of Thermodynamics 4.9.7Heat Engines, Heat Pumps & Refrigerators 4.9.8Non-Flow Processes 4.9.9p-V Diagrams 4.9.10Ideal Gases 4.9.11Ideal Gases 2 4.9.12Thermal Energy Transfer 4.9.13Thermal Energy Transfer Experiments

4.10

Materials

4.10.1Density 4.10.2Stress & Strain 4.10.3Properties of Materials 4.10.4Elasticity 4.10.5Plasticity 4.10.6Energy in Materials 4.10.7Young Modulus

4.11

Fluids

4.11.1Fluid Flow 4.11.2Viscosity 4.11.3Density 4.11.4Continuity Equation 4.11.5Bernoulli's Equation 4.11.6Non-Newtonian Fluids

5

Contemporary Issues in Science

5.1

Contemporary Issues in Science

5.1.1Sustainability 5.1.2Genetic Engineering 5.1.3Uses of Genetic Modification 5.1.4Stem Cell Therapy 5.1.5Cloning 5.1.6Cloning 2 5.1.7Nanotechnology 5.1.8Ecosystems

5.2

Analysing Scientific Information

5.2.1Validity 5.2.2Peer Review

Jump to other topics

1

Principles of Science I

1.1

Structure & Bonding

1.1.1Atomic Model 1.1.2Electron Shells, Sub-Shells & Orbitals 1.1.3Ionic Bonding 1.1.4Representing Ionic Bonds 1.1.5Covalent Bonding 1.1.6Representing Covalent Bonds 1.1.7Metallic Bonding 1.1.8Intermolecular Forces 1.1.9Intermolecular Forces 2 1.1.10End of Topic Test - Bonding 1.1.11Relative Masses 1.1.12The Mole 1.1.13Molar Calculations 1.1.14Molar Calculations 2 1.1.15Empirical & Molecular Formulae 1.1.16Balanced Equations 1.1.17Percentage Yield 1.1.18End of Topic Test - Amount of Substance

1.2

Properties of Substances

1.2.1The Periodic Table 1.2.2Ionisation Energy 1.2.3Factors Affecting Ionisation Energies 1.2.4Trends of Ionisation 1.2.5Trends in the Periodic Table 1.2.6Polarity 1.2.7Metals & Non-Metals 1.2.8Alkali Metals 1.2.9Alkaline Earth Metals 1.2.10Reactivity of Alkaline Earth Metals 1.2.11Redox 1.2.12Transition Metals 1.2.13Redox Reactions of Transition Metals

1.3

Cell Structure & Function

1.3.1Introduction to Cells 1.3.2Prokaryotes 1.3.3Organelles of Eukaryotic Cells 1.3.4Organelles of Eukaryotic Cells 2 1.3.5Organelles in Plant Cells 1.3.6Microscopy 1.3.7End of Topic Test - Cell Structure

1.4

Cell Specialisation

1.4.1Cell Specialisation 1.4.2Blood Cells 1.4.3Plant Cells 1.4.4Gametes

1.5

Tissue Structure & Function

1.5.1Human Gas Exchange 1.5.2Blood Vessels 1.5.3Atherosclerosis 1.5.4Skeletal Muscle 1.5.5Slow & Fast Twitch Fibres 1.5.6Neurones 1.5.7Speed of Transmission 1.5.8Action Potentials 1.5.9End of Topic Test - Neurones & Action Potentials 1.5.10Synapses 1.5.11Types of Synapse 1.5.12Medical Application 1.5.13End of Topic Test - Synapses 1.5.14Chemical Brain Imbalances 1.5.15Effect of Drugs on the Brain

1.6

Working with Waves

1.6.1Progressive Waves 1.6.2Wave Speed & Phase Difference 1.6.3Longitudinal & Transverse Waves 1.6.4Stationary Waves 1.6.5Stationary Waves 2 1.6.6Applications of Stationary Waves 1.6.7Interference 1.6.8Diffraction 1.6.9Diffraction Gratings 1.6.10Application of Diffraction Gratings

1.7

Waves in Communication

1.7.1Refraction at a Plane Surface 1.7.2Internal Reflection & Fibre Optics 1.7.3Applications of Total Internal Reflection 1.7.4Properties 1.7.5Gamma, X-Ray & UV Light 1.7.6Visible Light 1.7.7Infrared, Microwave & Radio Waves 1.7.8Intensity 1.7.9Digital & Analogue Signals 1.7.10Communication Channels

2

Practical Scientific Procedures and Techniques

2.1

Titration

2.1.1pH Curves & Titrations 2.1.2pH Curves & Titrations 2 2.1.3Buffer Solutions

2.2

Colorimetry

2.2.1Measuring Rates 2.2.2Beer-Lambert Law

2.3

Chromatography

2.3.1Overview of Chromatography 2.3.2Thin-Layer Chromatography 2.3.3Column Chromatography 2.3.4Gas Chromatography

3

Science Investigation Skills

3.1

Scientific Processes

3.1.1Aims, Hypotheses & Sampling 3.1.2Pilot Studies & Design 3.1.3Ethics 3.1.4Variables & Control 3.1.5Demand Characteristics & Investigator Effects 3.1.6Features of Science 3.1.7Scientific Report 3.1.8Scientific Report 2

3.2

Data Handling & Analysis

3.2.1Types of Data 3.2.2Descriptive Statistics 3.2.3Presentation & Display of Data

3.3

Enzymes in Action

3.3.1Overview of Protein Structure 3.3.2Enzymes 3.3.3Factors Affecting Enzyme Activity 3.3.4Enzyme-Controlled Reactions

3.4

Diffusion

3.5

Plants & Their Environment

3.5.1Factors Affecting Plant Growth 3.5.2Measuring Number & Distribution of Species

3.6

Energy Content in Fuels

3.6.1Fractions 3.6.2Burning Hydrocarbons 3.6.3Combustion 3.6.4Energy 3.6.5Energy at Home 3.6.6Calorimetry

3.7

Electrical Circuits

3.7.1Circuit Diagrams & Components 3.7.2Diodes, LDRs & Thermistors 3.7.3Resistance 3.7.4Electrical Work 3.7.5Ohm's Law 3.7.6Domestic Uses of Electricity 3.7.7Fuses

4

Principles of Science II

4.1

Extracting Elements

4.1.1Atom Economy

4.2

Relating Properties to use of Substances

4.2.1Group 2 Chemistry 4.2.2End of Topic Test - Group 2 4.2.3Electrolysis 4.2.4Electrolysis Examples 4.2.5Extracting Metals 4.2.6Transition Metals 4.2.7Variable Oxidation States 4.2.8Heterogeneous Catalysts 4.2.9Homogeneous Catalysts

4.3

Organic Chemistry

4.3.1Naming Compounds 4.3.2Functional Groups 4.3.3Isomerism 4.3.4Hydrocarbons 4.3.5Structure of Alkanes 4.3.6Boiling Points of Alkanes 4.3.7Alkenes 4.3.8Curly Arrows & Mechanisms 4.3.9Cracking 4.3.10Combustion 4.3.11Free Radical Substitution of Alkanes 4.3.12Electrophilic Addition of Alkenes

4.4

Energy Changes in Industry

4.4.1The Kelvin Scale 4.4.2Enthalpy Changes 4.4.3Calorimetry 4.4.4Bond Enthalpies 4.4.5Hess' Law

4.5

The Circulatory System

4.5.1The Circulatory System 4.5.2Blood Vessels 4.5.3Blood Transfusion & the ABO Rhesus System 4.5.4The Heart 4.5.5The Cardiac Cycle 4.5.6Cardiac Output 4.5.7Coordination of Heart Action 4.5.8Heart Dissection 4.5.9Controlling Heart Rate 4.5.10Electrocardiograms 4.5.11Cardiovascular Disease 4.5.12Investigating Heart Rates

4.6

Ventilation & Gas Exchange

4.6.1Human Gas Exchange 4.6.2Ventilation 4.6.3Measuring Gas Exchange 4.6.4Controlling Ventilation Rate 4.6.5Lung Disease 4.6.6Lung Disease Data

4.7

Urinary System

4.7.1Kidneys & Control of Water Balance 4.7.2Kidneys & Osmoregulation 4.7.3Kidneys & Blood Pressure 4.7.4Urine 4.7.5Kidney Failure & Urinalysis 4.7.6Dialysis 4.7.7Transplants

4.8

Cell Transport

4.8.1Cell Membrane Structure 4.8.2Diffusion 4.8.3Osmosis 4.8.4Active Transport

4.9

Thermal Physics

4.9.1Power & Efficiency 4.9.2Work & Energy 4.9.3Conservation of Energy 4.9.4Pressure 4.9.5First Law of Thermodynamics 4.9.6Second Law of Thermodynamics 4.9.7Heat Engines, Heat Pumps & Refrigerators 4.9.8Non-Flow Processes 4.9.9p-V Diagrams 4.9.10Ideal Gases 4.9.11Ideal Gases 2 4.9.12Thermal Energy Transfer 4.9.13Thermal Energy Transfer Experiments

4.10

Materials

4.10.1Density 4.10.2Stress & Strain 4.10.3Properties of Materials 4.10.4Elasticity 4.10.5Plasticity 4.10.6Energy in Materials 4.10.7Young Modulus

4.11

Fluids

4.11.1Fluid Flow 4.11.2Viscosity 4.11.3Density 4.11.4Continuity Equation 4.11.5Bernoulli's Equation 4.11.6Non-Newtonian Fluids

5

Contemporary Issues in Science

5.1

Contemporary Issues in Science

5.1.1Sustainability 5.1.2Genetic Engineering 5.1.3Uses of Genetic Modification 5.1.4Stem Cell Therapy 5.1.5Cloning 5.1.6Cloning 2 5.1.7Nanotechnology 5.1.8Ecosystems

5.2

Analysing Scientific Information

5.2.1Validity 5.2.2Peer Review

Practice questions on Trends in the Periodic Table

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1
The radius of which of the following actually increases as we go down a group?Multiple choice
2
Which of the following is NOT true as we go down a group?Multiple choice
3
Across a period:Fill in the list
4
Why does the distance between electrons and nuclei increase down a group?Multiple choice
5
Iodine is in Period 5 and chlorine is in Period 3. Which has a bigger radius?Multiple choice

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Trends of Ionisation

Polarity